Enantioenriched a-stannylated benzyl carbamates were used in highly stereospecific coupling reactions employing Cu(I) as catalyzing transition metal. Acid chlorides and allyl bromide derivatives were used as electrophilic coupling partners. The reaction was applied in the synthesis of two highly enantioenriched indanoles and one enantioenriched tetraline via intramolecular cyclization reactions.

Lange, H., Fröhlich, R., Hoppe, D. (2008). Cu(I)-catalyzed stereospecific coupling reactions of enantioenriched α-stannylated benzyl carbamates and their application. TETRAHEDRON, 64(38), 9123-9135 [10.1016/j.tet.2008.06.092].

Cu(I)-catalyzed stereospecific coupling reactions of enantioenriched α-stannylated benzyl carbamates and their application

Lange, H;
2008

Abstract

Enantioenriched a-stannylated benzyl carbamates were used in highly stereospecific coupling reactions employing Cu(I) as catalyzing transition metal. Acid chlorides and allyl bromide derivatives were used as electrophilic coupling partners. The reaction was applied in the synthesis of two highly enantioenriched indanoles and one enantioenriched tetraline via intramolecular cyclization reactions.
Articolo in rivista - Articolo scientifico
C–C coupling, Benzylic stannanes, Intramolecular cyclization reactions, Indanoles, Tetralines;
English
2008
64
38
9123
9135
reserved
Lange, H., Fröhlich, R., Hoppe, D. (2008). Cu(I)-catalyzed stereospecific coupling reactions of enantioenriched α-stannylated benzyl carbamates and their application. TETRAHEDRON, 64(38), 9123-9135 [10.1016/j.tet.2008.06.092].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/318845
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