C-Glycosyl methylenemalonates 2 and 4, useful precursors for the synthesis of glycopeptides and glycoproteins mimics, are obtained by reaction of a malonyl radical on the glycoexoenitols 1 and 3; reaction of the same radical with 6-deoxy-1,2: 3,4-di-O-isopropylidene-beta-L-arabino- hex-5-enopyranose 5 results in a mixture of the malonylderivatives 6, 7 and 8 and, in diluted THF solutions, also in the tetrahydrofuranyl derivative 9.

Cipolla, L., Liguori, L., Nicotra, F., Torri, G., & Vismara, E. (1996). Glycomimetics via a new glycoexoenitols-malonyl radical C-C bond formation. CHEMICAL COMMUNICATIONS(10), 1253-1254 [10.1039/cc9960001253].

Glycomimetics via a new glycoexoenitols-malonyl radical C-C bond formation

CIPOLLA, LAURA FRANCESCA;NICOTRA, FRANCESCO;
1996

Abstract

C-Glycosyl methylenemalonates 2 and 4, useful precursors for the synthesis of glycopeptides and glycoproteins mimics, are obtained by reaction of a malonyl radical on the glycoexoenitols 1 and 3; reaction of the same radical with 6-deoxy-1,2: 3,4-di-O-isopropylidene-beta-L-arabino- hex-5-enopyranose 5 results in a mixture of the malonylderivatives 6, 7 and 8 and, in diluted THF solutions, also in the tetrahydrofuranyl derivative 9.
Articolo in rivista - Articolo scientifico
C-glycosides; glycomimetics, radical reaction
English
1253
1254
2
Cipolla, L., Liguori, L., Nicotra, F., Torri, G., & Vismara, E. (1996). Glycomimetics via a new glycoexoenitols-malonyl radical C-C bond formation. CHEMICAL COMMUNICATIONS(10), 1253-1254 [10.1039/cc9960001253].
Cipolla, L; Liguori, L; Nicotra, F; Torri, G; Vismara, E
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/31745
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