Micellar catalysis enables carrying out Suzuki-Miyaura couplings in water under exceptionally mild conditions. Extension of such a protocol to the sustainable synthesis of highly conjugated, poorly soluble materials like [1]benzothieno[3,2-b][1]benzothiophene (BTBT) requires redesigning of the surfactants employed. The here reported new naphthalenediimide containing amphiphilic derivative, PiNap-750M, features unprecedented performances in the preparation of this and other relevant classes of organic semiconductors in water and at room temperature.

Sanzone, A., Mattiello, S., Maria Garavaglia, G., Calascibetta, A., Ceriani, C., Sassi, M., et al. (2019). Efficient synthesis of organic semiconductors by Suzuki-Miyaura coupling in an aromatic micellar medium. GREEN CHEMISTRY, 21(16), 4400-4405 [10.1039/c9gc01071h].

Efficient synthesis of organic semiconductors by Suzuki-Miyaura coupling in an aromatic micellar medium

Alessandro Sanzone;Sara Mattiello;Adiel Calascibetta;Chiara Ceriani;Mauro Sassi
;
Luca Beverina
2019

Abstract

Micellar catalysis enables carrying out Suzuki-Miyaura couplings in water under exceptionally mild conditions. Extension of such a protocol to the sustainable synthesis of highly conjugated, poorly soluble materials like [1]benzothieno[3,2-b][1]benzothiophene (BTBT) requires redesigning of the surfactants employed. The here reported new naphthalenediimide containing amphiphilic derivative, PiNap-750M, features unprecedented performances in the preparation of this and other relevant classes of organic semiconductors in water and at room temperature.
Articolo in rivista - Articolo scientifico
catalisi micellare, semiconduttori organici, green chemistry
English
4400
4405
6
Sanzone, A., Mattiello, S., Maria Garavaglia, G., Calascibetta, A., Ceriani, C., Sassi, M., et al. (2019). Efficient synthesis of organic semiconductors by Suzuki-Miyaura coupling in an aromatic micellar medium. GREEN CHEMISTRY, 21(16), 4400-4405 [10.1039/c9gc01071h].
Sanzone, A; Mattiello, S; Maria Garavaglia, G; Calascibetta, A; Ceriani, C; Sassi, M; Beverina, L
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/262296
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