We describe the functionalization of the layered perovskite HLaNb2O7 with n-propanol, n-decanol, 3-mercaptopropyl-trimethoxysilane, imidazole, n-decylamine, and histamine. The use of sonication is found to significantly improve the reaction yield and to reduce the reaction time, compared to conventional thermal treatment under reflux. The obtained intercalates are thoroughly characterized through the use of several complementary experimental techniques (scanning electron microscopy, IR spectroscopy, X-ray diffraction, thermogravimetric analysis, magic-angle spinning NMR), clarifying their structure and chemical bonding. The implications for the design of inorganic-organic composite materials are discussed.
Giannici, F., Mossuto Marculescu, A., Cattaneo, A., Tealdi, C., Mustarelli, P., Longo, A., et al. (2017). Covalent and Ionic Functionalization of HLN Layered Perovskite by Sonochemical Methods. INORGANIC CHEMISTRY, 56(1), 645-653 [10.1021/acs.inorgchem.6b02581].
Covalent and Ionic Functionalization of HLN Layered Perovskite by Sonochemical Methods
Cattaneo, AS;Mustarelli, P;
2017
Abstract
We describe the functionalization of the layered perovskite HLaNb2O7 with n-propanol, n-decanol, 3-mercaptopropyl-trimethoxysilane, imidazole, n-decylamine, and histamine. The use of sonication is found to significantly improve the reaction yield and to reduce the reaction time, compared to conventional thermal treatment under reflux. The obtained intercalates are thoroughly characterized through the use of several complementary experimental techniques (scanning electron microscopy, IR spectroscopy, X-ray diffraction, thermogravimetric analysis, magic-angle spinning NMR), clarifying their structure and chemical bonding. The implications for the design of inorganic-organic composite materials are discussed.
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