The Suzuki-Miyaura cross-coupling reaction of 4,7-dibromo-5,6-difluoro-2,1,3-benzothiadiazole with different arylboronic acids can be efficiently carried out in water and under air by means of micellar coupling. The careful tuning of reaction conditions enables preparation of symmetrically and unsymmetrically substituted derivatives. The moderate to good yields obtained, along with the wide variety of available substitution patterns, makes this sustainable methodology very useful for the preparation of building blocks for luminescent optoelectronic materials

Sanzone, A., Calascibetta, A., Ghiglietti, E., Ceriani, C., Mattioli, G., Mattiello, S., et al. (2018). Suzuki-Miyaura Micellar One-Pot Synthesis of Symmetrical and Unsymmetrical 4,7-Diaryl-5,6-difluoro-2,1,3-benzothiadiazole Luminescent Derivatives in Water and under Air. JOURNAL OF ORGANIC CHEMISTRY, 83(24), 15029-15042 [10.1021/acs.joc.8b02204].

Suzuki-Miyaura Micellar One-Pot Synthesis of Symmetrical and Unsymmetrical 4,7-Diaryl-5,6-difluoro-2,1,3-benzothiadiazole Luminescent Derivatives in Water and under Air

Sanzone, Alessandro
Primo
;
CALASCIBETTA, ADIEL MAURO;Ghiglietti, Erika;CERIANI, CHIARA;Mattiello, Sara;Sassi, Mauro;Beverina, Luca
2018

Abstract

The Suzuki-Miyaura cross-coupling reaction of 4,7-dibromo-5,6-difluoro-2,1,3-benzothiadiazole with different arylboronic acids can be efficiently carried out in water and under air by means of micellar coupling. The careful tuning of reaction conditions enables preparation of symmetrically and unsymmetrically substituted derivatives. The moderate to good yields obtained, along with the wide variety of available substitution patterns, makes this sustainable methodology very useful for the preparation of building blocks for luminescent optoelectronic materials
Articolo in rivista - Articolo scientifico
Suzuki-Miyaura, Green Chemistry, Benzothiadiazole;
English
15029
15042
14
Sanzone, A., Calascibetta, A., Ghiglietti, E., Ceriani, C., Mattioli, G., Mattiello, S., et al. (2018). Suzuki-Miyaura Micellar One-Pot Synthesis of Symmetrical and Unsymmetrical 4,7-Diaryl-5,6-difluoro-2,1,3-benzothiadiazole Luminescent Derivatives in Water and under Air. JOURNAL OF ORGANIC CHEMISTRY, 83(24), 15029-15042 [10.1021/acs.joc.8b02204].
Sanzone, A; Calascibetta, A; Ghiglietti, E; Ceriani, C; Mattioli, G; Mattiello, S; Sassi, M; Beverina, L
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/215211
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