A solventless mechanochemical methodology for the oxidation of electron-poor fluorinated anilines to the corresponding symmetrical azo compounds has been developed. In this process phenyliodine(III)diacetate and inexpensive calcium hypochlorite demonstrate to be good oxidants, providing the desired fluorinated azobenzenes in satisfactory yields, within short reaction times and avoiding the use of environmental unfriendly metal reagents.

Andreosso, I., Papagni, A., & Vaghi, L. (2018). Mechanochemical oxidation of fluorinated anilines to symmetric azobenzenes. JOURNAL OF FLUORINE CHEMISTRY, 216, 124-127 [10.1016/j.jfluchem.2018.10.012].

Mechanochemical oxidation of fluorinated anilines to symmetric azobenzenes

Andreosso, Ivan;Papagni, Antonio;Vaghi, Luca
2018

Abstract

A solventless mechanochemical methodology for the oxidation of electron-poor fluorinated anilines to the corresponding symmetrical azo compounds has been developed. In this process phenyliodine(III)diacetate and inexpensive calcium hypochlorite demonstrate to be good oxidants, providing the desired fluorinated azobenzenes in satisfactory yields, within short reaction times and avoiding the use of environmental unfriendly metal reagents.
Articolo in rivista - Articolo scientifico
Calcium hypochlorite; Fluorinated anilines; Fluorinated azobenzenes; Mechanochemistry; Oxidation; Phenyliodine(III)diacetate;
Fluorinated azobenzenes, Mechanochemistry, Oxidation, Fluorinated anilines, Phenyliodine(III)diacetate, Calcium hypochlorite
English
124
127
4
Andreosso, I., Papagni, A., & Vaghi, L. (2018). Mechanochemical oxidation of fluorinated anilines to symmetric azobenzenes. JOURNAL OF FLUORINE CHEMISTRY, 216, 124-127 [10.1016/j.jfluchem.2018.10.012].
Andreosso, I; Papagni, A; Vaghi, L
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/214291
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