An unsupported uranium-rhenium bond has been prepared by alkane elimination by treatment of a cyclometallated alkyl uranium triamidoamine complex with rhenocene hydride (see scheme). DFT analysis reveals σ and π combinations in the U-Re bond, but the rhenium contributions dominate and an atoms-in-molecules analysis reveals a closed-shell, predominantly ionic uranium-rhenium interaction. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

Gardner, B., Mcmaster, J., Moro, F., Lewis, W., Blake, A., Liddle, S. (2011). An unsupported uranium-rhenium complex prepared by alkane elimination. CHEMISTRY-A EUROPEAN JOURNAL, 17(25), 6909-6912 [10.1002/chem.201100682].

An unsupported uranium-rhenium complex prepared by alkane elimination

Moro, Fabrizio;
2011

Abstract

An unsupported uranium-rhenium bond has been prepared by alkane elimination by treatment of a cyclometallated alkyl uranium triamidoamine complex with rhenocene hydride (see scheme). DFT analysis reveals σ and π combinations in the U-Re bond, but the rhenium contributions dominate and an atoms-in-molecules analysis reveals a closed-shell, predominantly ionic uranium-rhenium interaction. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Articolo in rivista - Articolo scientifico
alkane elimination; density functional calculations; metal-metal bonding; rhenium; uranium; Chemistry (all)
English
2011
17
25
6909
6912
none
Gardner, B., Mcmaster, J., Moro, F., Lewis, W., Blake, A., Liddle, S. (2011). An unsupported uranium-rhenium complex prepared by alkane elimination. CHEMISTRY-A EUROPEAN JOURNAL, 17(25), 6909-6912 [10.1002/chem.201100682].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/210653
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