(Chemical Equation Presented) A straightforward oxidation strategy affords the first pentavalent uranium carbene complex, 2. Owing to the structural similarity of 1 and 2, it was possible for the first time to directly probe the differences in U=C bonding on oxidation of UIVto UV. © 2011 Wiley-VCH Verlag GmbH & Co. KGaA

Cooper, O., Mills, D., Mcmaster, J., Moro, F., Davies, E., Lewis, W., et al. (2011). Uranium-carbon multiple bonding: Facile access to the pentavalent uranium carbene [UC(PPh2NSiMe3)2(Cl)2(I)] and comparison of UV=C and UIV=C bonds. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 50(10), 2383-2386 [10.1002/anie.201007675].

Uranium-carbon multiple bonding: Facile access to the pentavalent uranium carbene [UC(PPh2NSiMe3)2(Cl)2(I)] and comparison of UV=C and UIV=C bonds

Moro, F;
2011

Abstract

(Chemical Equation Presented) A straightforward oxidation strategy affords the first pentavalent uranium carbene complex, 2. Owing to the structural similarity of 1 and 2, it was possible for the first time to directly probe the differences in U=C bonding on oxidation of UIVto UV. © 2011 Wiley-VCH Verlag GmbH & Co. KGaA
Articolo in rivista - Articolo scientifico
Carbene ligands; F-block elements; Metallo-Wittig reactivity; Multiple bonding; Uranium complexes; Catalysis; Chemistry (all)
English
2011
50
10
2383
2386
none
Cooper, O., Mills, D., Mcmaster, J., Moro, F., Davies, E., Lewis, W., et al. (2011). Uranium-carbon multiple bonding: Facile access to the pentavalent uranium carbene [UC(PPh2NSiMe3)2(Cl)2(I)] and comparison of UV=C and UIV=C bonds. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 50(10), 2383-2386 [10.1002/anie.201007675].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/210597
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