From a review of existing correlations for K(P) the partition coefficient of semi-volatile organic chemicals (SOCs) between aerosol and gaseous phases, it is suggested that the octanol-air partition coefficient (K(OA)) may be a valuable direct descriptor of SOCs volatility and may be preferable to the use of the experimentally inaccessible subcooled liquid-vapor pressure. Successful two parameter correlations are developed between log K(P) and log K(OA), and an even simpler one parameter correlation is suggested that the ratio K(P)/K(OA) is approximately constant for a class of SOCs
Finizio, A., Mackay, D., Bidleman, T., & Harner, T. (1997). Octanol-air partition coefficient as a predictor of partitioning of semi-volatile organic chemicals to aerosols. ATMOSPHERIC ENVIRONMENT, 31(15), 2289-2296 [10.1016/S1352-2310(97)00013-7].
Citazione: | Finizio, A., Mackay, D., Bidleman, T., & Harner, T. (1997). Octanol-air partition coefficient as a predictor of partitioning of semi-volatile organic chemicals to aerosols. ATMOSPHERIC ENVIRONMENT, 31(15), 2289-2296 [10.1016/S1352-2310(97)00013-7]. | |
Tipo: | Articolo in rivista - Articolo scientifico | |
Carattere della pubblicazione: | Scientifica | |
Presenza di un coautore afferente ad Istituzioni straniere: | Si | |
Titolo: | Octanol-air partition coefficient as a predictor of partitioning of semi-volatile organic chemicals to aerosols | |
Autori: | Finizio, A; Mackay, D; Bidleman, T; Harner, T | |
Autori: | ||
Data di pubblicazione: | 1997 | |
Lingua: | English | |
Rivista: | ATMOSPHERIC ENVIRONMENT | |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1016/S1352-2310(97)00013-7 | |
Appare nelle tipologie: | 01 - Articolo su rivista |