A mild and selective procedure for the synthesis of 4-carboxy thiazoles and thiazolidines starting from naturally occurring cysteine by condensation with aldehydes is described. The optimized procedure, taking advantage of the positive effect of microwave irradiation on the MnO2-mediated oxidation step, is suitable for multigram scale. Coordination of these ligands towards a variety of transition metal ions gave new interesting metallorganic supramolecular architectures in which an extensive 3D network is created through hydrogen bonding. Copyright © Taylor and Francis Group, LLC.
Di Credico, B., Gonsalvi, L., Peruzzini, M., Reginato, G., Rossin, A. (2011). Design and synthesis of thiazole and thiazolidine metallo-supramolecular networks. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 186(5), 1312-1315 [10.1080/10426507.2010.530327].
Design and synthesis of thiazole and thiazolidine metallo-supramolecular networks
Di Credico, B;
2011
Abstract
A mild and selective procedure for the synthesis of 4-carboxy thiazoles and thiazolidines starting from naturally occurring cysteine by condensation with aldehydes is described. The optimized procedure, taking advantage of the positive effect of microwave irradiation on the MnO2-mediated oxidation step, is suitable for multigram scale. Coordination of these ligands towards a variety of transition metal ions gave new interesting metallorganic supramolecular architectures in which an extensive 3D network is created through hydrogen bonding. Copyright © Taylor and Francis Group, LLC.
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