Combinations of two enantiomerically pure organic tectons 1 and 3 with either Zn(II) or Cu(II) cations lead to the formation of four homochiral 3D networks among which two, 1-Cu and 3-Cu, are robust porous crystals displaying homochiral cavities and permanent microporosity. 3-Cu porous crystals capture 66% and 20% of l- and d-tryptophan, respectively, after 30 min of adsorption
Asnaghi, D., Corso, R., Larpent, P., Bassanetti, I., Jouaiti, A., Kyritsakas, N., et al. (2017). Molecular tectonics: Gas adsorption and chiral uptake of (L)- and (D)-tryptophan by homochiral porous coordination polymers. CHEMICAL COMMUNICATIONS, 53(42), 5740-5743 [10.1039/c7cc01554b].
Molecular tectonics: Gas adsorption and chiral uptake of (L)- and (D)-tryptophan by homochiral porous coordination polymers
Asnaghi, DonataPrimo
Membro del Collaboration Group
;Bassanetti, IreneMembro del Collaboration Group
;Comotti, Angiolina
Membro del Collaboration Group
;Sozzani, Piero
Membro del Collaboration Group
;
2017
Abstract
Combinations of two enantiomerically pure organic tectons 1 and 3 with either Zn(II) or Cu(II) cations lead to the formation of four homochiral 3D networks among which two, 1-Cu and 3-Cu, are robust porous crystals displaying homochiral cavities and permanent microporosity. 3-Cu porous crystals capture 66% and 20% of l- and d-tryptophan, respectively, after 30 min of adsorption
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2017_ChemCommun_10.1039-c7cc01554b_SOZZANI.pdf
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