The C-glycosidic analogue of α-L-rhamnose 1-phosphate has been stereoselectively synthesised reacting 2,3,4-tri-O-benzyl-L-rhamnopyranose with tetraethyl methylenediphosphonate and sodium hydride in diglyme, and then deprotecting with iodotrimethylsilane.
Cipolla, L., LA FERLA, B., Nicotra, F., & Panza, L. (1997). Easy and Stereoselective Synthesis of the Phosphono Analogue of a-L-Rhamnose 1-phosphate. TETRAHEDRON LETTERS, 5567-5568.
Easy and Stereoselective Synthesis of the Phosphono Analogue of a-L-Rhamnose 1-phosphate
CIPOLLA, LAURA FRANCESCA;LA FERLA, BARBARA;NICOTRA, FRANCESCO;
1997
Abstract
The C-glycosidic analogue of α-L-rhamnose 1-phosphate has been stereoselectively synthesised reacting 2,3,4-tri-O-benzyl-L-rhamnopyranose with tetraethyl methylenediphosphonate and sodium hydride in diglyme, and then deprotecting with iodotrimethylsilane.
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