Deprotected C-glycopyranosyl-ketones have been conjugated by a chemoselective approach to a peptide or an amino acid bearing an aminooxy group on the N-terminus or on the side-chain, respectively. The coupling reaction, performed in aqueous media, does not require protecting groups on the peptide or saccharide moieties, nor auxiliary coupling reagents.
Peri, F., Cipolla, L., LA FERLA, B., Dumy, P., Nicotra, F. (1999). A highly convergent approach to O- and N-linked glycopeptide analogues. GLYCOCONJUGATE JOURNAL, 16(8), 399-404 [10.1023/A:1007026527040].
A highly convergent approach to O- and N-linked glycopeptide analogues
PERI, FRANCESCO;CIPOLLA, LAURA FRANCESCA;LA FERLA, BARBARA;NICOTRA, FRANCESCO
1999
Abstract
Deprotected C-glycopyranosyl-ketones have been conjugated by a chemoselective approach to a peptide or an amino acid bearing an aminooxy group on the N-terminus or on the side-chain, respectively. The coupling reaction, performed in aqueous media, does not require protecting groups on the peptide or saccharide moieties, nor auxiliary coupling reagents.
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