Attempts to synthesise α-C-glycosides of N-acetylgalactosamine by selective deprotection at C-2' of allyl α-C-galactoside 1 and subsequent amination failed, but opened the way to α-C-talopyranosides. The synthesis of α-C-glycosides of N-acetylgalactosamine was performed from allyl α-C-glucopyranoside 9, which was regioselectively deprotected, stereoselectively aminated at C-2', and finally epimerised at C-4'. Copyright (C) 2000 Elsevier Science Ltd.

Cipolla, L., LA FERLA, B., Lay, L., Peri, F., & Nicotra, F. (2000). Stereoselective synthesis of alfa-C-glycosides of N-acetylgalactosamine. TETRAHEDRON-ASYMMETRY, 11(1), 295-303 [10.1016/S0957-4166(99)00480-2].

Stereoselective synthesis of alfa-C-glycosides of N-acetylgalactosamine

CIPOLLA, LAURA FRANCESCA;LA FERLA, BARBARA;PERI, FRANCESCO;NICOTRA, FRANCESCO
2000

Abstract

Attempts to synthesise α-C-glycosides of N-acetylgalactosamine by selective deprotection at C-2' of allyl α-C-galactoside 1 and subsequent amination failed, but opened the way to α-C-talopyranosides. The synthesis of α-C-glycosides of N-acetylgalactosamine was performed from allyl α-C-glucopyranoside 9, which was regioselectively deprotected, stereoselectively aminated at C-2', and finally epimerised at C-4'. Copyright (C) 2000 Elsevier Science Ltd.
Articolo in rivista - Articolo scientifico
Scientifica
C-Glycosides, Glycomimetics
English
Cipolla, L., LA FERLA, B., Lay, L., Peri, F., & Nicotra, F. (2000). Stereoselective synthesis of alfa-C-glycosides of N-acetylgalactosamine. TETRAHEDRON-ASYMMETRY, 11(1), 295-303 [10.1016/S0957-4166(99)00480-2].
Cipolla, L; LA FERLA, B; Lay, L; Peri, F; Nicotra, F
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/10281/16589
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