Recently, oxygen-equilibrated water solutions of Kolliphor EL, a well-known surfactant, have been seen to form nanomicelles with oxygen-free cores. This has prompted the successful testing of the core environment as a green medium for palladium-catalyzed Suzuki-Miyaura cross couplings. The versatility of these conditions is endorsed by several examples, including the synthesis of relevant molecular semiconductors. The reaction medium can also be recycled, opening the way for an extremely easy and green chemistry compliant methodology.

Mattiello, S., Rooney, M., Sanzone, A., Brazzo, P., Sassi, M., Beverina, L. (2017). Suzuki-Miyaura Micellar Cross-Coupling in Water, at Room Temperature, and under Aerobic Atmosphere. ORGANIC LETTERS, 19(3), 654-657 [10.1021/acs.orglett.6b03817].

Suzuki-Miyaura Micellar Cross-Coupling in Water, at Room Temperature, and under Aerobic Atmosphere

MATTIELLO, SARA
Primo
;
ROONEY, MILES;SANZONE, ALESSANDRO;BRAZZO, PAOLO;SASSI, MAURO
Penultimo
;
BEVERINA, LUCA
2017

Abstract

Recently, oxygen-equilibrated water solutions of Kolliphor EL, a well-known surfactant, have been seen to form nanomicelles with oxygen-free cores. This has prompted the successful testing of the core environment as a green medium for palladium-catalyzed Suzuki-Miyaura cross couplings. The versatility of these conditions is endorsed by several examples, including the synthesis of relevant molecular semiconductors. The reaction medium can also be recycled, opening the way for an extremely easy and green chemistry compliant methodology.
Articolo in rivista - Articolo scientifico
Biochemistry; Physical and Theoretical Chemistry; Organic Chemistry;
English
2017
19
3
654
657
partially_open
Mattiello, S., Rooney, M., Sanzone, A., Brazzo, P., Sassi, M., Beverina, L. (2017). Suzuki-Miyaura Micellar Cross-Coupling in Water, at Room Temperature, and under Aerobic Atmosphere. ORGANIC LETTERS, 19(3), 654-657 [10.1021/acs.orglett.6b03817].
File in questo prodotto:
File Dimensione Formato  
Mattiello-2017-Org Lett-AAM.pdf

accesso aperto

Descrizione: Letter
Tipologia di allegato: Author’s Accepted Manuscript, AAM (Post-print)
Dimensione 5.7 MB
Formato Adobe PDF
5.7 MB Adobe PDF Visualizza/Apri
Mattiello-2017-Org Lett-VoR.pdf

Solo gestori archivio

Descrizione: Letter
Tipologia di allegato: Publisher’s Version (Version of Record, VoR)
Dimensione 2.21 MB
Formato Adobe PDF
2.21 MB Adobe PDF   Visualizza/Apri   Richiedi una copia

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/150166
Citazioni
  • Scopus 55
  • ???jsp.display-item.citation.isi??? 54
Social impact