Recently, oxygen-equilibrated water solutions of Kolliphor EL, a well-known surfactant, have been seen to form nanomicelles with oxygen-free cores. This has prompted the successful testing of the core environment as a green medium for palladium-catalyzed Suzuki-Miyaura cross couplings. The versatility of these conditions is endorsed by several examples, including the synthesis of relevant molecular semiconductors. The reaction medium can also be recycled, opening the way for an extremely easy and green chemistry compliant methodology.

Mattiello, S., Rooney, M., Sanzone, A., Brazzo, P., Sassi, M., & Beverina, L. (2017). Suzuki-Miyaura Micellar Cross-Coupling in Water, at Room Temperature, and under Aerobic Atmosphere. ORGANIC LETTERS, 19(3), 654-657 [10.1021/acs.orglett.6b03817].

Suzuki-Miyaura Micellar Cross-Coupling in Water, at Room Temperature, and under Aerobic Atmosphere

MATTIELLO, SARA
Primo
;
ROONEY, MILES;SANZONE, ALESSANDRO;BRAZZO, PAOLO;SASSI, MAURO
Penultimo
;
BEVERINA, LUCA
2017

Abstract

Recently, oxygen-equilibrated water solutions of Kolliphor EL, a well-known surfactant, have been seen to form nanomicelles with oxygen-free cores. This has prompted the successful testing of the core environment as a green medium for palladium-catalyzed Suzuki-Miyaura cross couplings. The versatility of these conditions is endorsed by several examples, including the synthesis of relevant molecular semiconductors. The reaction medium can also be recycled, opening the way for an extremely easy and green chemistry compliant methodology.
No
Articolo in rivista - Articolo scientifico
Scientifica
Biochemistry; Physical and Theoretical Chemistry; Organic Chemistry;
English
654
657
4
Mattiello, S., Rooney, M., Sanzone, A., Brazzo, P., Sassi, M., & Beverina, L. (2017). Suzuki-Miyaura Micellar Cross-Coupling in Water, at Room Temperature, and under Aerobic Atmosphere. ORGANIC LETTERS, 19(3), 654-657 [10.1021/acs.orglett.6b03817].
Mattiello, S; Rooney, M; Sanzone, A; Brazzo, P; Sassi, M; Beverina, L
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/10281/150166
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