The separation of 1,3-butadiene from C4hydrocarbon mixtures is imperative for the production of synthetic rubbers, and there is a need for a more economical separation method, such as a pressure swing adsorption process. With regard to adsorbents that enable C4gas separation, [Zn(NO2ip)(dpe)]n(SD-65; NO2ip=5-nitroisophthalate, dpe=1,2-di(4-pyridyl)ethylene) is a promising porous material because of its structural flexibility and restricted voids, which provide unique guest-responsive accommodation. The 1,3-butadiene-selective sorption profile of SD-65 was elucidated by adsorption isotherms, in situ PXRD, and SSNMR studies and was further investigated by multigas separation and adsorption–desorption-cycle experiments for its application to separation technology.
Kishida, K., Okumura, Y., Watanabe, Y., Mukoyoshi, M., Bracco, S., Comotti, A., et al. (2016). Recognition of 1,3-Butadiene by a Porous Coordination Polymer. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 55(44), 13784-13788.
Citazione: | Kishida, K., Okumura, Y., Watanabe, Y., Mukoyoshi, M., Bracco, S., Comotti, A., et al. (2016). Recognition of 1,3-Butadiene by a Porous Coordination Polymer. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 55(44), 13784-13788. |
Tipo: | Articolo in rivista - Articolo scientifico |
Carattere della pubblicazione: | Scientifica |
Presenza di un coautore afferente ad Istituzioni straniere: | Si |
Titolo: | Recognition of 1,3-Butadiene by a Porous Coordination Polymer |
Autori: | Kishida, K; Okumura, Y; Watanabe, Y; Mukoyoshi, M; Bracco, S; Comotti, A; Sozzani, P; Horike, S; Kitagawa, S |
Autori: | |
Data di pubblicazione: | 2016 |
Lingua: | English |
Rivista: | ANGEWANDTE CHEMIE. INTERNATIONAL EDITION |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1002/anie.201607676 |
Appare nelle tipologie: | 01 - Articolo su rivista |
File in questo prodotto:
File | Descrizione | Tipologia | Licenza | |
---|---|---|---|---|
AngewChem_submission 08-08-16.pdf | Submitted version | Preprint | Open Access Visualizza/Apri |