Vibrational spectroscopy of OH-defects in sol-gel Ce3 and Gd3+doped silicate glasses

Vibrational modes of OH, as stretching, bending, combination, and overtones, were monitored by means of FTIR spectroscopy in Ce3 - and Gd3 -doped silicate glasses, prepared by means of the sol-gel technique, submitted to different thermal treatments, and aimed to applications as scintillators. The dopant concentration was varied in a wide range (10 -3 -8% m.f.) and co-doped samples were also investigated. In this framework, the effects of OH and of rare-earth (RE) clustering, i.e. two possible non-radiative decay channels, on the IR spectra in the 500-14 000 cm(-1) were examined. OH was detected as belonging either to water and to silanol in samples densified at 450 and 750 degreesC, while in those treated at 1050 degreesC only Si-OH groups were present in a concentration of the order of 1% m.f., nearly regardless of the RE amount. An absorption peaking at 4250 cm(-1) was identified as related to an OH combination mode (bending???) perturbed by a Gd cluster on the basis of its amplitude dependence on the Gd concentration and rapid thermal treatment.