We report on the synthesis and characterization of new crosslinked polymeric matrices, pertaining to the class of poly(amide-amine)s (PAAs), functionalized with highly performing nonlinear optical (NLO) heterocycle-based dyes as side-chain substituents. Linear, soluble, and highly crosslinked NLO-functionalized PAA networks can be easily prepared under mild conditions. The wide-ranging tunability of optical and mechanical properties of these matrices makes them a superior alternative to conventional high T-g thermoplastic polymers.
Abbotto, A., Beverina, L., Chirico, G., Facchetti, A., Ferruti, P., Gilberti, M., et al. (2003). Crosslinked poly(amido-amine)s as superior matrices for chemical incorporation of highly efficient organic nonlinear optical dyes. MACROMOLECULAR RAPID COMMUNICATIONS, 24(5-6), 397-402 [10.1002/marc.200390057].
Crosslinked poly(amido-amine)s as superior matrices for chemical incorporation of highly efficient organic nonlinear optical dyes
ABBOTTO, ALESSANDRO;BEVERINA, LUCA;CHIRICO, GIUSEPPE;PAGANI, GIORGIO ALBERTO
2003
Abstract
We report on the synthesis and characterization of new crosslinked polymeric matrices, pertaining to the class of poly(amide-amine)s (PAAs), functionalized with highly performing nonlinear optical (NLO) heterocycle-based dyes as side-chain substituents. Linear, soluble, and highly crosslinked NLO-functionalized PAA networks can be easily prepared under mild conditions. The wide-ranging tunability of optical and mechanical properties of these matrices makes them a superior alternative to conventional high T-g thermoplastic polymers.
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