The surface-assisted synthesis of gold-organometallic hybrids on the Au(111) surface both by thermo- and light-initiated dehalogenation of bromo-substituted tetracene is reported. Combined X-ray photoemission (XPS) and scanning tunneling microscopy (STM) data reveal a significant increase of the surface order when mild reaction conditions are combined with 405 nm light irradiation.

Basagni, A., Ferrighi, L., Cattelan, M., Nicolas, L., Handrup, K., Vaghi, L., et al. (2015). On-surface photo-dissociation of C-Br bonds: Towards room temperature Ullmann coupling. CHEMICAL COMMUNICATIONS, 51(63), 12593-12596 [10.1039/c5cc04317d].

On-surface photo-dissociation of C-Br bonds: Towards room temperature Ullmann coupling

FERRIGHI, LARA
Secondo
;
VAGHI, LUCA;PAPAGNI, ANTONIO;DI VALENTIN, CRISTIANA;
2015

Abstract

The surface-assisted synthesis of gold-organometallic hybrids on the Au(111) surface both by thermo- and light-initiated dehalogenation of bromo-substituted tetracene is reported. Combined X-ray photoemission (XPS) and scanning tunneling microscopy (STM) data reveal a significant increase of the surface order when mild reaction conditions are combined with 405 nm light irradiation.
Articolo in rivista - Articolo scientifico
Chemistry (all); Catalysis; Ceramics and Composites; Electronic, Optical and Magnetic Materials; Surfaces, Coatings and Films; Materials Chemistry2506 Metals and Alloys; 2506
English
2015
51
63
12593
12596
partially_open
Basagni, A., Ferrighi, L., Cattelan, M., Nicolas, L., Handrup, K., Vaghi, L., et al. (2015). On-surface photo-dissociation of C-Br bonds: Towards room temperature Ullmann coupling. CHEMICAL COMMUNICATIONS, 51(63), 12593-12596 [10.1039/c5cc04317d].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/110769
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