The stepwise reaction of the ethylene-like molecule [Re2(μ-H) 2(CO)8] with [Pt(cod)2] (cod = cycloocta-1,5-diene) affords the triangular cluster [Re2Pt(μ-H) 2(CO)8(COd)] and then, under H2, the pentanuclear species [Re4Pt(μ-H)6(CO)16], with a bow-tie geometry of the metal cluster, which in basic media deprotonates reversibly to [Re4Pt(μ-H)5(CO)16] -.
Ciani, G., Moret, M., Sironi, A., Antognazza, P., Beringhelli, T., D'Alfonso, G., et al. (1991). Stepwise addition of [Re2(m-H)2(CO)8] to a labile Pt(0) complex. X-Ray crystal structures of the bow-tie clusters [Re4Pt(m-H)6-n)(CO)16]n- (n= 0,1). JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS, 1991, 1255-1257 [10.1039/C39910001255].
Citazione: | Ciani, G., Moret, M., Sironi, A., Antognazza, P., Beringhelli, T., D'Alfonso, G., et al. (1991). Stepwise addition of [Re2(m-H)2(CO)8] to a labile Pt(0) complex. X-Ray crystal structures of the bow-tie clusters [Re4Pt(m-H)6-n)(CO)16]n- (n= 0,1). JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS, 1991, 1255-1257 [10.1039/C39910001255]. | |
Tipo: | Articolo in rivista - Articolo scientifico | |
Carattere della pubblicazione: | Scientifica | |
Titolo: | Stepwise addition of [Re2(m-H)2(CO)8] to a labile Pt(0) complex. X-Ray crystal structures of the bow-tie clusters [Re4Pt(m-H)6-n)(CO)16]n- (n= 0,1) | |
Autori: | Ciani, G; Moret, M; Sironi, A; Antognazza, P; Beringhelli, T; D'Alfonso, G; Della Pergola, R; Minoja, A | |
Autori: | ||
Data di pubblicazione: | 1991 | |
Lingua: | English | |
Rivista: | JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS | |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1039/C39910001255 | |
Appare nelle tipologie: | 01 - Articolo su rivista |