The invention concerns a solid-state oxygen sensor in the form of an electrolytic cell with a first electrode exposed to the atmosphere containing the oxygen whose partial pressure is to be measured, a second electrode exposed to a reference atmosphere, and a solid electrolyte in surface contact with both electrodes. The electrolyte material is a ceramic oxide or glassy phase exhibiting pure ionic conduction, and at least the first electrode contains a non-stoichiometric ceramic oxide. The invention calls for the first electrode to be made of a mixture of at least one non-stoichiometric ceramic oxide and a metal, the latter being gold, platinum, nickel or chromium. A sensor of this kind can determine the oxygen partial pressure over a wide range of pressures and is sensitive to poisoning of the electrodes by carbon monoxide or lead.
Manes, L., Mari, C. (1989)Oxygen sensor with solid electrolyte. Brevetto No. LU19890087596.
Oxygen sensor with solid electrolyte
MARI, CLAUDIO MARIA
1989
Abstract
The invention concerns a solid-state oxygen sensor in the form of an electrolytic cell with a first electrode exposed to the atmosphere containing the oxygen whose partial pressure is to be measured, a second electrode exposed to a reference atmosphere, and a solid electrolyte in surface contact with both electrodes. The electrolyte material is a ceramic oxide or glassy phase exhibiting pure ionic conduction, and at least the first electrode contains a non-stoichiometric ceramic oxide. The invention calls for the first electrode to be made of a mixture of at least one non-stoichiometric ceramic oxide and a metal, the latter being gold, platinum, nickel or chromium. A sensor of this kind can determine the oxygen partial pressure over a wide range of pressures and is sensitive to poisoning of the electrodes by carbon monoxide or lead.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.


