Mixed ionic-electronic conductors (MIEC) are of growing interest for fuel cells, batteries and sensors. Here, by exploiting the unique properties of Li4C60 2D fulleride and poly(ethylene oxide) (PEO), we demonstrate the feasibility of a MIEC where the nature of transport can be tuned from ionic, to mixed, to almost entirely electronic, simply by changing the weight ratio of the two basic components. By coupling 7Li MAS-NMR, electrochemical impedance spectroscopy and open circuit voltage (OCV) measurements of a Li/composite/LiFePO4 cell we demonstrate that: i) a fraction of Li+ ions is extracted by Li4C60 and confined into PEO amorphous strands similarly to what happens in PEO-salt systems; ii) a transition between prevalently ionic and electronic conductivity takes place at 33 wt% Li4C60. This new class of MIEC is very promising for the design of both chemically and electrochemically stable semi-cells and interfaces which can be employed in batteries and supercapacitors.

Cattaneo, A., Dall'Asta, V., Pontiroli, D., Riccò, M., Magnani, G., Milanese, C., et al. (2016). Tailoring ionic-electronic transport in PEO-Li4C60: Towards a new class of all solid-state mixed conductors. CARBON, 100, 196-200 [10.1016/j.carbon.2016.01.009].

Tailoring ionic-electronic transport in PEO-Li4C60: Towards a new class of all solid-state mixed conductors

Cattaneo, AS;Mustarelli, P
2016

Abstract

Mixed ionic-electronic conductors (MIEC) are of growing interest for fuel cells, batteries and sensors. Here, by exploiting the unique properties of Li4C60 2D fulleride and poly(ethylene oxide) (PEO), we demonstrate the feasibility of a MIEC where the nature of transport can be tuned from ionic, to mixed, to almost entirely electronic, simply by changing the weight ratio of the two basic components. By coupling 7Li MAS-NMR, electrochemical impedance spectroscopy and open circuit voltage (OCV) measurements of a Li/composite/LiFePO4 cell we demonstrate that: i) a fraction of Li+ ions is extracted by Li4C60 and confined into PEO amorphous strands similarly to what happens in PEO-salt systems; ii) a transition between prevalently ionic and electronic conductivity takes place at 33 wt% Li4C60. This new class of MIEC is very promising for the design of both chemically and electrochemically stable semi-cells and interfaces which can be employed in batteries and supercapacitors.
Articolo in rivista - Articolo scientifico
Chemistry (all)
English
2016
100
196
200
reserved
Cattaneo, A., Dall'Asta, V., Pontiroli, D., Riccò, M., Magnani, G., Milanese, C., et al. (2016). Tailoring ionic-electronic transport in PEO-Li4C60: Towards a new class of all solid-state mixed conductors. CARBON, 100, 196-200 [10.1016/j.carbon.2016.01.009].
File in questo prodotto:
File Dimensione Formato  
2016-Carbon-Li4C60.pdf

Solo gestori archivio

Dimensione 605.68 kB
Formato Adobe PDF
605.68 kB Adobe PDF   Visualizza/Apri   Richiedi una copia

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/219382
Citazioni
  • Scopus 10
  • ???jsp.display-item.citation.isi??? 10
Social impact