Supramolecular chemistry finds in solid-state NMR spectroscopy a privileged characterization method, especially in a variety of multidimensional experiments. Several applications of solid-state NMR to inclusion compounds, host–guest systems, cocrystals, polymeric self-assembly, and porous materials have been realized. Gases and volatile molecules were detected in supramolecular adducts by NMR as well, providing accurate information about their interaction with the solid transport properties and anisotropic behavior. In ordered systems, the results are complementary to XRD and, thus, NMR is regarded as a structural method, but it is also sensitive to amorphous phases, complex molecular aggregates, interfaces, and overall dynamics.
Comotti, A., Bracco, S., Sozzani, P. (2017). Solid-State NMR of Supramolecular Materials. In Editor-in-Chiefs: Jerry Atwood Editors: George W. Gokel Len Barbour (a cura di), Solid-State NMR of Supramolecular Materials. In: Comprehensive Supramolecular Chemistry II, (pp. 75-99). Elsevier.
Solid-State NMR of Supramolecular Materials
Comotti, A;Bracco, SMembro del Collaboration Group
;Sozzani, P
Membro del Collaboration Group
2017
Abstract
Supramolecular chemistry finds in solid-state NMR spectroscopy a privileged characterization method, especially in a variety of multidimensional experiments. Several applications of solid-state NMR to inclusion compounds, host–guest systems, cocrystals, polymeric self-assembly, and porous materials have been realized. Gases and volatile molecules were detected in supramolecular adducts by NMR as well, providing accurate information about their interaction with the solid transport properties and anisotropic behavior. In ordered systems, the results are complementary to XRD and, thus, NMR is regarded as a structural method, but it is also sensitive to amorphous phases, complex molecular aggregates, interfaces, and overall dynamics.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
