α- and β-C-allylgalactopyranosides 1c and 1d, α-C-allylazaglucopyranoside 1e and α-C-allylfruttofuranoside 1f were hydroformylated at low temperatures affording a mixture of linear and branched aldehydes in regioisomeric and diastereoisomeric ratios depending on the starting alkene. The results obtained have allowed us to study the influence of the different structural features of the sugar moiety on the regio- and diastereoselectivity of the hydroformylation reaction. © 2006 Elsevier B.V. All rights reserved.

Lazzaroni, R., Rocchiccioli, S., Iuliano, A., Cipolla, L. (2006). Substrate-directed asymmetric induction in the rhodium catalyzed hydroformylation of C-allyl-sugars: The influence of the glycoside-moiety on the selectivity of the reaction. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 691(19), 4054-4057 [10.1016/j.jorganchem.2006.06.008].

Substrate-directed asymmetric induction in the rhodium catalyzed hydroformylation of C-allyl-sugars: The influence of the glycoside-moiety on the selectivity of the reaction

CIPOLLA, LAURA FRANCESCA
2006

Abstract

α- and β-C-allylgalactopyranosides 1c and 1d, α-C-allylazaglucopyranoside 1e and α-C-allylfruttofuranoside 1f were hydroformylated at low temperatures affording a mixture of linear and branched aldehydes in regioisomeric and diastereoisomeric ratios depending on the starting alkene. The results obtained have allowed us to study the influence of the different structural features of the sugar moiety on the regio- and diastereoselectivity of the hydroformylation reaction. © 2006 Elsevier B.V. All rights reserved.
Articolo in rivista - Articolo scientifico
CARBOHYDRATES, ASYMMETRIC INDUCTION, HYDROFORMYLATION
English
2006
691
19
4054
4057
none
Lazzaroni, R., Rocchiccioli, S., Iuliano, A., Cipolla, L. (2006). Substrate-directed asymmetric induction in the rhodium catalyzed hydroformylation of C-allyl-sugars: The influence of the glycoside-moiety on the selectivity of the reaction. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 691(19), 4054-4057 [10.1016/j.jorganchem.2006.06.008].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10281/14439
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